Teoriya i metody rascheta molekulyarnych processov: Spektry, chimicheskie prevrashheniya i molekulyarnaya logika
Publishing country: Russia
Language: Russian
Author: Gribov L.A., Baranov V.I.
Publisher: KomKniga
Publishing city: Moskva
ISBN: 978-5-484-01526-9
Publishing year: 2019
Number of pages: 480
Binding: Hardback edition
Monografiya, baziruyushhayasya na rezul′tatach issledovanij avtorov, posvyashhena posledovatel′nomu izlozheniyu edinoj teorii molekulyarnych processov kak spektral′noj, tak i chimicheskoj prirody. Razvityj podchod osnovan na vvedenii energeticheskich matric, ob′′edinyayushhich charakteristiki sostoyanij molekulyarnych podsistem raznogo tipa. Dlya opisaniya processov predlagaetsya sovokupnost′ kineticheskich differencial′nych uravnenij pervogo poryadka, koefficientami kotorych yavlyayutsya veroyatnosti spektral′nych i bezyzluchatel′nych chimicheskich prevrashhenij. Pokazano, chto s odnoj i toj zhe tochki zreniya udaetsya opisat′ vazhnejshie osobennosti, nablyudayushhiesya v opticheskich spektrach vysokogo vremennogo razresheniya (piko- i femtosekundnych), pri fotoizomerizacii, pri chimicheskich prevrashheniyach. Na baze pervych principov vyvoditsya zakon Arreniusa, obosnovyvaetsya pravilo lokal′nosti chimicheskich prevrashhenij v bol′shich molekulach (reakcionnye centry) i t.d. Analiz sledstvij obshhej teorii pozvolyaet sformulirovat′ prostye pravila choda chimicheskich reakcij i poiska ich putej. Issleduetsya mechanizm peredachi informacii i energii v molekulyarnom prostranstve. Special′naya glava posvyashhena voprosam preobrazovaniya molekulami vchodnoj informacii, vklyuchaya zadannuyu v nechetkom vide, raspoznavaniyu molekulami obrazov, dejstviyu molekulyarnych logicheskich elementov i dr. Pokazany celesoobraznost′ i puti razvitiya na toj zhe teoreticheskoj osnove novogo napravleniya - molekulyarnoj logiki - s cel′yu sozdaniya molekulyarnych priemno-preobrazuyushhich informacionnych sistem. Kniga rasschitana na specialistov v oblasti kvantovoj chimii i teorii opticheskich spektrov slozhnych molekul, aspirantov i studentov starshich kursov fizicheskich i chimicheskich fakul′tetov vuzov.
Publishing country: Russia
Language: Russian
Themes by country: Russia
Author: Gribov L.A., Baranov V.I.
Publisher: KomKniga
Publishing city: Moskva
ISBN: 978-5-484-01526-9
Publishing year: 2019
Number of pages: 480
Binding: Hardback edition
Stage: PUBLISHED
Format: Printed book
Delivery time: 4-6 weeks
Monografiya, baziruyushhayasya na rezul′tatach issledovanij avtorov, posvyashhena posledovatel′nomu izlozheniyu edinoj teorii molekulyarnych processov kak spektral′noj, tak i chimicheskoj prirody. Razvityj podchod osnovan na vvedenii energeticheskich matric, ob′′edinyayushhich charakteristiki sostoyanij molekulyarnych podsistem raznogo tipa. Dlya opisaniya processov predlagaetsya sovokupnost′ kineticheskich differencial′nych uravnenij pervogo poryadka, koefficientami kotorych yavlyayutsya veroyatnosti spektral′nych i bezyzluchatel′nych chimicheskich prevrashhenij. Pokazano, chto s odnoj i toj zhe tochki zreniya udaetsya opisat′ vazhnejshie osobennosti, nablyudayushhiesya v opticheskich spektrach vysokogo vremennogo razresheniya (piko- i femtosekundnych), pri fotoizomerizacii, pri chimicheskich prevrashheniyach. Na baze pervych principov vyvoditsya zakon Arreniusa, obosnovyvaetsya pravilo lokal′nosti chimicheskich prevrashhenij v bol′shich molekulach (reakcionnye centry) i t.d. Analiz sledstvij obshhej teorii pozvolyaet sformulirovat′ prostye pravila choda chimicheskich reakcij i poiska ich putej. Issleduetsya mechanizm peredachi informacii i energii v molekulyarnom prostranstve. Special′naya glava posvyashhena voprosam preobrazovaniya molekulami vchodnoj informacii, vklyuchaya zadannuyu v nechetkom vide, raspoznavaniyu molekulami obrazov, dejstviyu molekulyarnych logicheskich elementov i dr. Pokazany celesoobraznost′ i puti razvitiya na toj zhe teoreticheskoj osnove novogo napravleniya - molekulyarnoj logiki - s cel′yu sozdaniya molekulyarnych priemno-preobrazuyushhich informacionnych sistem. Kniga rasschitana na specialistov v oblasti kvantovoj chimii i teorii opticheskich spektrov slozhnych molekul, aspirantov i studentov starshich kursov fizicheskich i chimicheskich fakul′tetov vuzov.
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